土壤中总有机碳环境标准样品研制     

王尧  田衎  封跃鹏  王伟 《岩矿测试》2021,(4):593-602

土壤环境标准样品是土壤生态环境监测质量控制的重要技术工具。目前,土壤中总有机碳环境标准样品仍为中国环境标准样品体系的空缺,特别是配套燃烧氧化-非分散红外法的土壤标准样品一直未曾问世。本文以有机碳含量较高的农用地土壤为原材料,经干燥、研磨、混匀、装瓶、灭菌等加工步骤,制备获得土壤中总有机碳环境标准样品。分层随机抽取10瓶样品进行均匀性检验,经评价统计量F小于临界值F_(0.05)(9,10),瓶间均匀性相对不确定度(u_(bb))为1.5%,样品均匀性良好。在室温避光保存条件下,对样品进行了18个月的稳定性检验,稳定性相对不确定度(u_(lts))为1.2%,样品具有良好稳定性。由中国11家实验室采用燃烧氧化-非分散红外法和重铬酸钾容量法进行协作定值,通过对检测结果的数理统计分析,样品量值评定结果为(25.2±1.4)mg/g。该标准样品为采用燃烧氧化-非分散红外法参与定值的土壤中总有机碳环境标准样品,可作为土壤中总有机碳测定标准方法配套的实物标准,满足土壤生态环境监测及相关研究需求,且与国外同类样品具有可比性。  相似文献   

热红外遥感技术在江西寻乌地区地热勘查中的应用     

任正情  方泓锦  王学平 《江苏地质》2021,45(3):277-282

热红外遥感是地热资源勘查中的常用技术,对江西寻乌地区的Landsat 8热红外影像采用单窗算法,根据MODIS影像计算大气水汽含量,并逐步获取反演参数,得到地表温度反演结果;利用MOD11_L2地表温度产品对结果进行对比分析,验证反演有效性。通过对已有地热资料和地质构造背景的研究,总结地热形成的有利构造条件,分析地表反演温度与已有地热及断裂构造之间的空间关系,建立地热异常区圈定依据,并剔除假异常,最终在研究区圈定了11个潜在地热异常区,为该区地热勘查提供依据。  相似文献   

短波红外光谱、X射线荧光光谱、黄铁矿热电性分析在胶东新城金矿田深部找矿中的应用     

邵雪维  彭永明  王功文  赵显勇  唐佳洋  黄蕾蕾  刘晓宁  赵宪东 《地学前缘》2021,28(3):236-251

胶东半岛是我国最重要的金矿集区之一,其矿床是典型受北东向断裂构造(焦家断裂带、三山岛断裂带和招平断裂带),以及次生断裂构造(如望儿山断裂和灵北断裂等)控制的矿床类型。前人在该区域做了大量研究,但主要集中在地表和浅层成矿段,对于深部成矿规律与预测的研究相对较少。新城金矿田是胶东半岛的特大型金矿之一,由新城矿床、曲家矿床和招贤矿床三部分组成。由于受到焦家断裂带控制,在招贤矿区中的科研深钻达到2 500 m以下,为我们研究深部成矿规律提供了良好的样品。本文通过该地区蚀变矿物的短波红外光谱特征(short-wave infrared spectroscopy,SWIR),并结合X 射线荧光光谱(X-ray fluorescence spectrometry,XRF)法和黄铁矿热电性法,选取该地的不同成矿阶段的蚀变岩石和典型载金矿物黄铁矿,并在三维环境中,定量化分析了主要的蚀变矿物——白云母族的短波红外光谱的特征值,揭示其找矿规律与指示意义,进一步提取矿床中蚀变矿物的找矿标志。研究结果表明:(1)在靠近焦家主断裂构造蚀变岩型矿体的位置,伊利石结晶度(≥1.2)和绢云母Al—OH吸收位置(≥2 205 nm)偏高,而在远离焦家主断裂构造蚀变岩型矿体的位置伊利石结晶度和绢云母Al—OH吸收位置偏低,分别为0.2~1.2和2 198~2 205 nm。(2)X 射线荧光光谱结果提取了该地区20种元素含量,通过对元素的主成分分析和聚类分析, Al—OH吸收峰位置偏移与Al、K、Si含量变化有一定相关性。(3)黄铁矿热电性导型在近焦家主断裂构造蚀变岩主要为P型,远离主断裂的主要为N型。在新城矿区的Ⅰ号和Ⅴ号矿体的顶部到底部整体呈现N-P→P→P-N→N→N-P→P-N和P-N→N-P的规律;在招贤矿区中绝大部分是P型。剥蚀度整体处于在25%~50%,因此在新城矿区约-800 m以下和招贤矿区约-1 500 m以下,仍有较好的深部找矿前景。整体上P型黄铁矿成矿温度主要为180~250 ℃,N型成矿温度主要区间值在380~460 ℃;利用温度场进行三维插值建模,其与三维矿体品位模型空间展布趋势一致。本文综合研究方法为深部矿产资源评价提供新的研究思路,将光谱数据、地化数据等多维度信息集成整合,同时使用三维模型可视化功能,对于矿产模型定量化构建具有重要参考价值。  相似文献   

Geology and mineralization of the Sanshandao supergiant gold deposit (1200 t) in the Jiaodong Peninsula,China: A review     

《China Geology》2021,4(4):686-719

The Jiaodong Peninsula in Shandong Province, China is the world’s third-largest gold metallogenic area, with cumulative proven gold resources exceeding 5000 t. Over the past few years, breakthroughs have been made in deep prospecting at a depth of 500–2000 m, particularly in the Sanshandao area where a huge deep gold orebody was identified. Based on previous studies and the latest prospecting progress achieved by the project team of this study, the following results are summarized. (1) 3D geological modeling results based on deep drilling core data reveal that the Sanshandao gold orefield, which was previously considered to consist of several independent deposits, is a supergiant deposit with gold resources of more than 1200 t (including 470 t under the sea area). The length of the major orebody is nearly 8 km, with a greatest depth of 2312 m below sea level and a maximum length of more than 3 km along their dip direction. (2) Thick gold orebodies in the Sanshandao gold deposit mainly occur in the specific sections of the ore-controlling fault where the fault plane changes from steeply to gently inclined, forming a stepped metallogenic model from shallow to deep level. The reason for this strong structural control on mineralization forms is that when ore-forming fluids migrated along faults, the pressure of fluids greatly fluctuated in fault sections where the fault dip angle changed. Since the solubility of gold in the ore-forming fluid is sensitive to fluid pressure, these sections along the fault plane serve as the target areas for deep prospecting. (3) Thermal uplifting-extensional structures provide thermodynamic conditions, migration pathways, and deposition spaces for gold mineralization. Meanwhile, the changes in mantle properties induced the transformation of the geochemical properties of the lower crust and magmatic rocks. This further led to the reactivation of ore-forming elements, which provided rich materials for gold mineralization. (4) It can be concluded from previous research results that the gold mineralization in the Jiaodong gold deposits occurred at about 120 Ma, which was superimposed by nonferrous metals mineralization at 118–111 Ma. The fluids were dominated by primary mantle water or magmatic water. Metamorphic water occurred in the early stage of the gold mineralization, while the fluid composition was dominated by meteoric water in the late stage. The S, Pb, and Sr isotopic compositions of the ores are similar to those of ore-hosting rocks, indicating that the ore-forming materials mainly derive from crustal materials, with the minor addition of mantle-derived materials. The gold deposits in the Jiaodong Peninsula were formed in an extensional tectonic environment during the transformation of the physical and chemical properties of the lithospheric mantle, which is different from typical orogenic gold deposits. Thus, it is proposed that they are named “Jiaodong-type” gold deposits.©2021 China Geology Editorial Office.  相似文献   

白天和夜间通用的卫星遥感沙尘判识算法构建与验证分析     

王威  胡秀清  张鹏  闵敏 《气象》2019,45(12):1666-1679

Himawari-8是日本发射的新一代静止气象卫星,与前一代的MTSAT-2相比,在时间、空间分辨率上都有了很大提升,特别是红外通道数量从4个增至10个,为红外遥感沙尘提供了新的观测数据。本研究利用Himawari-8的红外观测数据,发展了仅用红外通道的沙尘全天候判识算法,可以实现对白天和夜间的连续监测。算法在前人基础上去除了可见光通道,同时引入更多红外通道来进行云检测和沙尘判识。由于一日之中,地表温度发生变化,因此针对白天和夜间设置了两套不同的判别阈值,来保证算法的全天适用性。最后通过两次沙尘事件对沙尘判别结果的分析和检验表明,遥感判识结果与地面气象站和PM_(10)观测较为一致,说明了只用红外通道全天候判识沙尘的可行性。  相似文献   

2017年6月一次华南沿海强降水的对流性特征及热动力机制研究          下载免费PDF全文

曾智琳  谌芸  朱克云 《大气科学》2019,43(6):1295-1312

在华南北部或长江流域有锋面雨带活动时,华南沿海常常会出现对流性强降水,突发性很强,给预报造成很大的困惑。文章采用多种观测资料、ERA-Interim 0.125°×0.125°逐6 h再分析资料,对2017年6月15～16日华南北部的锋面雨带及沿海强降雨过程开展分析,对比了二者降水特征与环境条件,重点探讨了该次过程华南沿海强降雨的对流触发与维持,揭示了一种由边界层风切变强迫造成涡度持续发展的动力效应。结果表明:（1）锋面雨带与华南沿海强降雨在降水特征上有显著差异,并各有特点。锋面雨带以大尺度层状云降水和弱对流性降水为主,降水强度东段弱西段强。沿海强降雨以对流性降水为主,局地性强、落区集中、强降雨持续时间长、夜发性明显。（2）水汽方程诊断发现沿海强降雨在边界层水平水汽平流项、垂直水汽输送项比锋面雨带东段具有更大量级,大气层结反映出更深厚的暖层、湿层与对流不稳定,是二者降水强度及性质差异的主要原因。（3）莲花山、峨眉嶂造成气流侧向摩擦与正面阻挡促使漯河河谷内垂直涡度发展,暖湿空气堆积上升并达到自由对流高度,触发了华南沿海最初的降水。夜间建立的西南风急流使边界层垂直风速切变增强,水平涡度倾斜部分转化为垂直涡度发展,与风速水平切变造成的垂直涡度叠加,是强降雨持续时间长的动力机制。海陆边界摩擦差异造成水平、垂直两个方向的风切变增强,共同强迫垂直涡度发展是此次强降雨过程对流维持的动力效应。（4）方程诊断表明华南沿海强降雨由对流潜热释放造成的垂直上升速度占总垂直上升速度的39%～75%,持续、稳定的对流潜热释放是强降雨持续时间长的热力驱动因素。  相似文献   

An Operational Precipitable Water Vapor Retrieval Algorithm for Fengyun-2F/VISSR Using a Modified Three-Band Physical Split-Window Method     

Juyang HU  Shihao TANG  Hailei LIU  Min MIN 《Journal of Meteorological Research》2019,(2):276-288

The Visible and Infrared Spin-Scan Radiometer(VISSR) onboard the Fengyun-2(FY-2) satellite can provide valuable thermal infrared observations to help create a precipitable water vapor(PWV) product with high spatial and temporal resolutions. The current FY-2/VISSR PWV product in operation is produced by using a traditional two-band physical split-window(PSW) method, which produces low quality results under dry atmospheric conditions. Based on the sensitivity characteristics of FY-2 F/VISSR water vapor channel and two split-window channels to atmospheric water vapor, this study developed a new, robust operational PWV retrieval algorithm for FY-2 F to improve the operational precision of the current PWV product. The algorithm uses a modified three-band PSW method, which adds a scale for the water vapor channel in the improved three-band PSW method. Integrated PWV products from the radiosonde data in 2016 are used here to validate the precision of the PWV retrieved by the modified three-band and traditional two-band PSW methods. The mean bias, root mean square error(RMSE), and correlation coefficient of the PWV retrieved by the modified three-band PSW method are 0.28 mm, 4.53 mm, and 0.969, respectively. The accuracy is much better than the PWV retrieved by the two-band method, whose mean bias, RMSE, and correlation coefficient are 12.67 mm, 29.35 mm, and 0.23. Especially, in mid-or high-latitude regions, the RMSE of the PWV is improved from 10 to 2 mm by changing the inversion in the two-band method to the modified three-band PSW method. Furthermore, the modified three-band PSW results show a better consistency with the radiosonde PWV at any zonal belt and season than the two-band PSW results. This new algorithm could significantly improve the quality of the current FY-2 F/VISSR PWV product, especially at sites where the actual PWV are lower than 15 mm.  相似文献   

基于晴空阈值法的全天空红外图像云量计算     

陈磊  张海波  石鹏飞  韩燕  关军 《沙漠与绿洲气象(新疆气象)》2015,9(3):50-56

为提高新疆戈壁地区云的自动化观测水平,基于全天空红外成像仪(WSIRCMS)获取的红外辐射图像,利用辐射传输模式SBDART分析了仪器测量波段对有云无云状况的敏感性并构建了拟合方程,同时利用典型季节的晴空辐射样本拟合了晴空曲线并统计形成了晴空阈值,最后利用统计晴空阈值对全天空红外辐射图像进行云像素识别和总云量计算。将不同季节总云量计算结果同人工观测结果对比验证表明：观测时段算法计算总云量和人工观测总云量差值在±2成以下的概率均在80%以上,说明该方法具有较高的准确度和较强的实用性,在观测业务中具有较好的应用前景。  相似文献   

基于压缩感知的地基红外云图云状识别   总被引：1，自引：0，他引：1       下载免费PDF全文

韩文宇  刘磊  高太长  李云  胡帅  张孝忠 《应用气象学报》2015,26(2):231-239

为了对地基全天空红外测云仪获得的云图进行分类,该文从压缩感知理论出发,提出了一种利用云图灰度稀疏性进行云状识别的新方法。首先运用典型云图样本构造冗余字典,然后通过梯度投影 (GPSR) 算法和正交匹配 (OMP) 算法求取测试样本在冗余字典中的l1范式最优解,最后利用残差法和稀疏比例法对云状进行判别并输出。采用压缩感知理论进行云状识别,降低了对特征提取技术的要求,为云状的自动识别提供了新思路,对典型波状云、层状云、积状云、卷云和晴空的总体识别率分别达到75%,91%,70%,85%和93%,平均识别率为82.8%。  相似文献   

东亚多卫星集成降水业务系统   总被引：2，自引：0，他引：2  

徐宾  师春香  姜立鹏  孟俊耀 《气象科技》2015,43(6):1007-1014

静止气象卫星与极轨气象卫星的集成应用,能够充分发挥静止气象卫星与极轨气象卫星的各自优势。东亚多卫星集成降水业务系统采用拉格朗日集成算法,利用静止气象卫星的红外观测信息计算的红外冷云移动矢量,为极轨气象卫星微波降水的发展提供约束条件,实现了静止气象卫星红外观测信息与极轨气象卫星微波降水的集成,综合了两类卫星观测的优势。同时业务系统的设计考虑了多数据分级管理、多业务单元的协同工作和插件式的系统整体框架,为业务系统合理、快速处理多种来源的红外观测数据、微波降水数据,以及未来的数据更迭和算法更新提供了必要保障。  相似文献